Ch 9 Atomic Foundations of Matter Question Answer Class 9 New NCERT

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Table of Contents

A particular element (A) has one electron in its third shell. There is another element (B) with six electrons in its second shell.


(i) How many electrons does A tend to give or take to become stable?
(ii) What kind of ion would it form?
(iii) How many electrons does B tend to give or take to become stable?
(iv) What kind of ion would it form?
(v) If A and B were to combine, what kind of bond would be formed?
(vi) What would be the formula for the compound thus formed?

(i) Element A gives away 1 electron to become stable.

(ii) A forms a cation (positively charged ion), because it loses an electron and is left with more protons than electrons.

(iii) Element B gains 2 electrons to complete its octet (it has 6 valence electrons and needs 8).

(iv) B forms an anion (negatively charged ion), because it gains electrons.

(v) An ionic bond would form, because A transfers its electron to B.

(vi) A has a charge of 1+ and B has a charge of 2. Using the criss-cross method:

A has a charge of 1+, and B has a charge of 2. Using the criss-cross method:

ElementSymbolCharge
A (like Na)A1+
B (like O)B2−

Formula = A B

An element X has six electrons in its outer shell and forms a diatomic
molecule.


(i) Why would that be so?
(ii) What kind of bond would it form?
(iii) Draw the structure of the molecule it would form.
(iv) A certain other element Y has two electrons in its second shell.

Draw the structure of the molecule that X would form with Y.

(i) X has 6 valence electrons and needs 2 more to complete its octet. Since it cannot get them from itself alone, two atoms of X share electrons with each other, forming a diatomic molecule.

(ii) A covalent bond — specifically a double bond, because two pairs of electrons are shared.

(iii) X = X (double covalent bond — two shared electron pairs)
This is similar to oxygen: O=O

Image showing formation of double bond for class 9



(iv) Y has 2 valence electrons and needs 6 more. X has 6 valence electrons and needs 2 more. So one X atom shares with two Y atoms, each giving one electron.
Structure: Y — X — Y (like H₂O, water)
Formula: YX (or XY, with 1 X and 2 Y atoms)

Image showing bonding in three atoms for class 9


(i)Source: Page 170, Para 2 — “two oxygen atoms share two electrons each, forming an oxygen molecule (O₂).”

(ii) Source: Page 170, Para 3 — “the two atoms are joined by two pairs of shared electrons, and are held together by a double bond… O=O.”

(iii) Source: Page 170, Fig. 9.8 — “Formation of an oxygen molecule.”

(iv) Source: Page 171, Para 1 and Fig. 9.10 — “two hydrogen atoms sharing an electron each with an oxygen atom… water molecule formed is represented as H₂O.”

You want to design a new ionic compound, where the total positive
charge is 6+ and the total negative charge is 6 –. Which of the following
combinations gives the correct number of ions?


(i) 2 Al3+ and 3 Cl
(ii) 3 Mg2+ and 1 PO43
(iii) 2 Fe3+ and 3 O2-
(iv) 3 Ca2+ and 2 SO42-

Checking each option:

OptionPositive ChargeNegative ChargeBalanced?
(i) 2 Al³⁺, 3 Cl⁻2×3 = 6+3×1 = 3−✗ No
(ii) 3 Mg²⁺, 1 PO₄³⁻3×2 = 6+1×3 = 3−✗ No
(iii) 2 Fe³⁺, 3 O²⁻2×3 = 6+3×2 = 6−✓ Yes
(iv) 3 Ca²⁺, 2 SO₄²⁻3×2 = 6+2×2 = 4−✗ No

Answer: (iii) 2 Fe³⁺ and 3 O²⁻

Choose the correct statement(s) and correct the false statement(s).


(i) Elements are made up of molecules, and compounds are made up of
of atoms.
(ii) The molecule of a compound is always made up of two or more
atoms of the same kind.
(iii) One molecule of nitrogen gas contains three nitrogen atoms.
(iv) Water is made of two hydrogen atoms, covalently bonded with
one oxygen atom.


(i) FALSE. Corrected: Elements are made up of atoms, and compounds are made up of molecules (formed by atoms of different elements).

(ii) FALSE. Corrected: A molecule of a compound is made up of atoms of different elements. (Two or more atoms of the same kind form a molecule of an element, not a compound.)

(iii) FALSE. Corrected: One molecule of nitrogen gas (N₂) contains two nitrogen atoms.
(vi) TRUE.

Write the chemical formulae for the following compounds.


(i) Aluminium nitrate
(ii) Calcium oxid
(iii) Ferric oxide

(i) Aluminium nitrate

IonSymbolCharge
AluminiumAl3+
NitrateNO₃1−

Criss-cross → Al( NO )

(ii)Calcium oxide

IonSymbolCharge
CalciumCa2+
OxideO2−

Equal charges → CaO

(iii) Ferric oxide

IonSymbolCharge
Iron (Ferric)Fe3+
OxideO2−

Criss-cross → FeO

Write the formulae of the compounds formed from the following pairs
of ions.

(i) Ca2+ and Br
(ii) Al3+ and CO32–
(iii) K+ and SO42–
(iv) NH4+and Cl

Which of the following, in Fig. 9.18, correctly represents Cl– ion (Atomic
number of chlorine = 17).

Chlorine (atomic number 17) has the electronic configuration: 2, 8, 7

Cl⁻ gains 1 electron, so it has 18 electrons arranged as: 2, 8, 8

The correct diagram must show:

  • 3 shells (K, L, M)
  • 2 electrons in the K-shell
  • 8 electrons in L-shell
  • 8 electrons in M-shell (not 7)

Answer: Option (ii) — whichever figure shows a 2, 8, 8 arrangement.

Determine the formula unit mass of the following substances.

(i) Ammonium nitrate (NH4NO3), used as a nitrogen fertiliser, which
is essential for plant growth.
(ii) Phosphoric acid (H3PO4), used to make phosphate fertiliser and
detergents.
(iii) Sodium hydrogencarbonate (NaHCO3), used to relieve acidity and
helps in digestion.

Atomic masses used:

mini · element box
Element
Sym
Mass (u)
Hydrogen
H
1
Carbon
C
12
Nitrogen
N
14
Oxygen
O
16
Sodium
Na
23
Phosphorus
P
31
Sulfur
S
32

(i) Ammonium nitrate (NH₄NO₃)

NH₄⁺: N=14, H×4=4 → 18u
NO₃⁻: N=14, O×3=48 → 62u
Total = 18 + 62 = 80u

Formula unit mass = 80 u


(ii) Phosphoric acid (H₃PO₄)

H×3 = 3u
P×1 = 31u
O×4 = 64u
Total = 3+31+64 = 98u

Formula unit mass = 98 u


(iii) Sodium hydrogencarbonate (NaHCO₃)

Na = 23u
H = 1u
C = 12u
O×3 = 48u
Total = 23+1+12+48 = 84u

Formula unit mass = 84 u

Write the formulae for the compounds formed by the reaction of:

(i) Magnesium and nitrogen
(ii) Lithium and nitrogen
(iii) Sodium and sulfur
(iv) Aluminium and oxygen

Using valencies from Table 9.1, page 174 of the textbook, exploration grade 9, and the criss-cross method:

ReactionIonsChargesFormula
(i) Magnesium + NitrogenMg²⁺, N³⁻2+, 3−Mg₃N₂
(ii) Lithium + NitrogenLi⁺, N³⁻1+, 3−Li₃N
(iii) Sodium + SulfurNa⁺, S²⁻1+, 2−Na₂S
(iv) Aluminium + OxygenAl³⁺, O²⁻3+, 2−Al₂O₃

Complete the Table 9.3 by writing the formulae of the compounds
formed by the cations on the left and the anions at the top. LiNO3 is
given as an example.

example.

Anions
Cations
NO₃⁻ (1−)SO₄²⁻ (2−)PO₄³⁻ (3−)
NH₄⁺ (1+)NH₄NO₃(NH₄)₂SO₄(NH₄)₃PO₄
Li⁺ (1+)LiNO₃Li₂SO₄Li₃PO₄
Al³⁺ (3+)Al(NO₃)₃Al₂(SO₄)₃AlPO₄
Cu²⁺ (2+)Cu(NO₃)₂CuSO₄Cu₃(PO₄)₂

5.3 g of sodium carbonate and 6.0 g of acetic acid react to produce 2.2 g
of carbon dioxide, 0.9 g of water, and 8.2 g of sodium acetate.
Verify whether the law of conservation of mass is valid.

Total mass of REACTANTS:

Sodium carbonate = 5.3 g
Acetic acid = 6.0 g

TOTAL = 11.3 g

Total mass of PRODUCTS:

Carbon dioxide = 2.2 g
Water = 0.9 g
Sodium acetate = 8.2 g

TOTAL = 11.3 g

Mass of reactants = Mass of products = 11.3 g ✓

Conclusion: The Law of Conservation of Mass is valid.

If a species has 11 protons, 12 neutrons, and 10 electrons, then

(i) What is its atomic number and mass number?
(ii) Is it neutral, a cation, or an anion? Explain.
(iii) Write its electronic configuration.
(iv) Name the species.

(i)Atomic number = Number of protons = 11
Mass number = Protons + Neutrons = 11 + 12 = 23

(ii) It is a cation. Protons (11) > Electrons (10) → net positive charge of 1+

(iii) 10 electrons arranged as: 2, 8
(K-shell = 2, L-shell = 8)

(iv) This is Na⁺ (Sodium cation / Sodium ion). Atomic number 11 = Sodium. It has lost one electron to become Na⁺.

(i)Source: Page 182, Q12 data — atomic number = protons.
(ii) Source: Page 172, Para 3 — “it would have 11 protons and 10 electrons… becomes a positively charged species, called a sodium cation, represented as Na⁺.”
(iii) 2n2
(iv)Source: Page 172, Para 3 — “sodium cation, represented as Na⁺.”

Two elements, A and B, have the following configurations —

A: 2, 8, 5 | B: 2, 8, 7

(i) Which element is more reactive?
(ii) Will A and B form ionic or covalent bonds when they combine?
Explain using electron transfer or sharing.
(iii) Predict the formula of the compound they would form.

(i) B is more reactive. B has 7 valence electrons and needs only 1 more to complete its octet. It is very close to stability, making it highly reactive. A has 5 valence electrons and needs 3 more — harder to achieve.

(ii) They will form a covalent bond by sharing electrons. A needs 3 electrons; B needs 1 electron. Both have more than 4 valence electrons, so they tend to share, not transfer

(iii) A needs 3 electrons; B needs 1. So 1 atom of A shares with 3 atoms of B.

Formula: AB

Assertion (A): Copper sulfate conducts electricity in the molten state
but not in the solid state.

Reason (R): Copper and sulfate ions are fixed in the lattice in molten
state, while in solid state they can move freely.


Choose the correct option:

(i) Both A and R are true, and R is the correct explanation of A.
(ii) Both A and R are true, but R is not the correct explanation of A.
(iii) A is true, but R is false.
(iv) A is false, but R is true.

(iii) A is true, but R is false.

Explanation:

  • The Assertion is correct — ionic compounds like copper sulfate do conduct in the molten state but not in the solid state.
  • The Reason is incorrectly stated — it has the states reversed. In the solid state, ions are fixed (cannot move). In the molten state, ions are free to move and carry current.

The species 27Al, 80Br and 201Hg2+ have 13, 35, and 80 protons, respectively.
How many electrons and neutrons do they have?

hey have?

SpeciesProtonsMass NumberNeutrons
(Mass − Protons)
ChargeElectrons
²⁷Al132727−13 = 14Neutral13
⁸⁰Br⁻358080−35 = 451− (gained 1e)36
²⁰¹Hg²⁺80201201−80 = 1212+ (lost 2e)78

Source: Page 172–173 — “When a sodium atom loses its valence electron, it becomes a positively charged species… After gaining one extra electron, it acquires a negative charge.”

What is the Law of Conservation of Mass, and does it apply to all chemical reactions?

The Law of Conservation of Mass states that mass can neither be created nor destroyed in a chemical reaction. The total mass of reactants always equals the total mass of products. It was proposed by Antoine Lavoisier in 1789 and applies to every chemical reaction — provided the system is closed (no gas escapes).

Example from the chapter (Page 165–166):

ReactantsMass
Calcium carbonate4.0 g
Hydrochloric acid2.92 g
Total6.92 g
ProductsMass
Carbon dioxide1.76 g
Water0.72 g
Calcium chloride4.44 g
Total6.92 g

Mass of reactants = Mass of products = 6.92 g

“If I burn paper and nothing is left, does mass disappear?”

No.
The paper converts to carbon dioxide and water vapour, which escape into the air. The system must be closed to observe mass conservation directly. In an open system, gases escape, and the reading appears to drop — but mass is still conserved across the entire universe.

The Law of Conservation of Mass states that mass can neither be created nor destroyed in a chemical reaction. The total mass of reactants always equals the total mass of products. It was proposed by Antoine Lavoisier in 1789 and applies to every chemical reaction — provided the system is closed (no gas escapes).

Experimental Set-up 2 fixed this by sealing the gas inside a balloon attached to the flask, and the mass remained constant. (Page 164–165)

QuestionAnswer
Who proposed it?Antoine Lavoisier, 1789
What does it say?Mass of reactants = Mass of products
Does it apply always?Yes — in a closed system
What if gas escapes?Mass seems to drop, but is conserved overall
Chapter referencePage 165, Section 9.1

What is the difference between a covalent bond and an ionic bond — and how do you know which one a compound has?

A covalent bond forms when atoms share electrons. An ionic bond forms when one atom transfers electrons to another, creating oppositely charged ions that attract each other. The key rule: atoms with more than 4 valence electrons tend to share (covalent); atoms with fewer than 4 tend to transfer (ionic).

Comparison Table:

FeatureCovalent BondIonic Bond
How it formsSharing of electronsTransfer of electrons
Who forms itNon-metals + Non-metalsMetals + Non-metals
ExampleH₂O, HCl, O₂NaCl, CaCl₂, MgO
Melting/Boiling pointLowHigh
Solubility in waterVariesGenerally soluble
Solubility in kerosene/petrolGenerally solubleInsoluble
Conducts electricity (solid)?NoNo
Conducts electricity (dissolved in water)?No (mostly)Yes
State at room tempOften liquid/gasSolid crystals

Real-Life examples:

CompoundBond TypeWhere You Find It
Table salt (NaCl)IonicYour kitchen
Water (H₂O)CovalentEverywhere
Sugar (C₁₂H₂₂O₁₁)CovalentYour tea/coffee
Copper sulfateIonicSchool lab (blue crystals)
NaphthaleneCovalentOld mothballs

Why dissolved salt conducts electricity but sugar does not (from Think It Over, Page 162):

Answer: Salt (NaCl) breaks into free ions (Na⁺ and Cl⁻) in water — these ions carry electric current. Sugar dissolves in water but produces no ions — so no current flows.

How do you write chemical formulae of ionic and covalent compounds using the criss-cross method?

The criss-cross method swaps the valency (or charge) of each element and writes it as the subscript of the other element. For ionic compounds, use the ion charges. For covalent compounds, use the valencies. Always simplify subscripts by dividing by any common factor.
Step-by-Step: The Criss-Cross Method
STEP 1: Write symbols of both elements/ions
STEP 2: Write their charges/valencies below
STEP 3: Swap (criss-cross) the numbers
STEP 4: Write swapped numbers as subscripts
STEP 5: Simplify if both subscripts share a common factor
STEP 6: Use brackets for polyatomic ions appearing more than once
(Source: Page 175–177, Section 9.5)

Worked Examples Table:

CompoundIons/ElementsChargesAfter Criss-CrossSimplified Formula
Calcium chlorideCa, Cl2+, 1−Ca₁Cl₂CaCl₂
Aluminium oxideAl, O3+, 2−Al₂O₃Al₂O₃
Magnesium oxideMg, O2+, 2−Mg₂O₂MgO
Magnesium hydroxideMg, OH2+, 1−Mg₁(OH)₂Mg(OH)₂
Aluminium sulfateAl, SO₄3+, 2−Al₂(SO₄)₃Al₂(SO₄)₃
Hydrogen sulfideH, S1, 2H₂S₁H₂S

Golden Rules — Never Forget:

  1. If subscript = 1, don’t write it (e.g., MgO, not Mg₁O₁)
  2. If both subscripts have a common factor, divide both (Mg₂O₂ → MgO)
  3. Use brackets only when a polyatomic ion appears more than once (e.g., Mg(OH)₂)
  4. Charges are not shown in the final formula

Naming Covalent Compounds — Prefix Quick Guide:

Number of AtomsPrefixExample
1mono- (omit for first element)Carbon monoxide (CO)
2di-Carbon dioxide (CO₂)
3tri-Phosphorus trichloride (PCl₃)
4tetra-Carbon tetrachloride (CCl₄)
5penta-Dinitrogen pentoxide (N₂O₅)
6hexa-Sulfur hexafluoride (SF₆)

What is the Law of Constant Proportions, and how is it different from the Law of Conservation of Mass?

The Law of Constant Proportions (proposed by Joseph Proust) states that a compound always contains the same elements in the same fixed mass ratio, regardless of its source or how it was made. The Law of Conservation of Mass (by Lavoisier) says mass is neither created nor destroyed in a reaction. One is about ratio of elements; the other is about total mass.

The Clearest Comparison:

FeatureLaw of Conservation of MassLaw of Constant Proportions
Proposed byAntoine Lavoisier (1789)Joseph Proust
Also calledLaw of Definite Proportions / Proust’s Law
What it saysMass before = Mass after reactionElements in a compound are always in fixed mass ratio
AboutTotal mass of a reactionComposition of a compound
Example6.92g reactants → 6.92g productsWater is always H:O = 1:8 by mass
Applies toAll chemical reactionsAll pure compounds

(Source: Page 165 Section 9.1; Page 167 Section 9.2)

Water — The Perfect Example (Page 167):

No matter where water comes from — a river, a borewell, the ocean, or a lab — when purified and analysed, it always contains:

Hydrogen : Oxygen = 1 : 8 (by mass)

9g of water always gives:
→ 1g Hydrogen
→ 8g Oxygen

This never changes. Ever. That is Proust’s Law in action.

Why This Matters in Real Life:

ScenarioWhich Law Applies?
A student burns magnesium in a closed container — mass stays the sameConservation of Mass
Water from a river and water from a lab both have H:O = 1:8Constant Proportions
CO₂ formed from any source always has C:O = 12:32 (3:8)Constant Proportions
Reactants weigh 50g → Products must weigh 50gConservation of Mass

Fascinating Historical Insight from the Chapter (Page 167 — Threads of Curiosity):

The mineral cinnabar (called hingula in India) was used as red pigment in ancient civilisations. When heated, it always yielded mercury and sulfur in the ratio 86.22% : 13.78% — a perfect real-world demonstration of the Law of Constant Proportions, observed independently across cultures thousands of years ago.

How do you calculate molecular mass and formula unit mass — and what is the difference between the two?

Molecular mass is the total mass of one molecule of a covalent compound, found by adding the atomic masses of all atoms in it. Formula unit mass is used for ionic compounds (which don’t form individual molecules), and equals the sum of atomic masses in the simplest ion ratio (formula unit). Both are measured in atomic mass units (u).

The Core Difference:

FeatureMolecular MassFormula Unit Mass
Used forCovalent compoundsIonic compounds
Why different?Covalent compounds form distinct moleculesIonic compounds form 3D crystal lattices — no single molecule exists
How to calculateAdd atomic masses of all atoms in formulaAdd atomic masses of all atoms in formula unit
Unitu (atomic mass units)u (atomic mass units)
Example compoundH₂O, CO₂, CH₄NaCl, Na₂O, Ca(NO₃)₂

(Source: Page 179–180, Sections 9.7 and 9.8)

Step-by-Step Calculation Method:

Solved Examples — At a Glance:

CompoundFormulaCalculationMass
WaterH₂O(1×2) + (16×1)18 u
Carbon dioxideCO₂(12×1) + (16×2)44 u
Sodium oxideNa₂O(23×2) + (16×1)62 u
Calcium nitrateCa(NO₃)₂(40×1) + [(14×1)+(16×3)]×2164 u
Nitric acidHNO₃(1×1)+(14×1)+(16×3)63 u
MethaneCH₄(12×1)+(1×4)16 u

Atomic Mass Reference Card (Most Used):

ElementSymbolAtomic Mass
HydrogenH1 u
CarbonC12 u
NitrogenN14 u
OxygenO16 u
SodiumNa23 u
MagnesiumMg24 u
PhosphorusP31 u
SulfurS32 u
ChlorineCl35.5 u
PotassiumK39 u
CalciumCa40 u

Why Ionic Compounds Don’t Have “Molecular Mass”:

Ionic compounds like NaCl do not exist as individual molecules. They form giant 3D crystal lattices where 6 Cl ions surround each Na, and 6 Na ions surround each Cl. There is no single “NaCl molecule” — just a repeating pattern extending in all directions.

This is why we use formula unit mass — it refers to the mass of just one formula unit (the simplest ratio: 1 Na⁺ and 1 Cl⁻), not a standalone molecule.

(Source: Page 173, Threads of Curiosity — “Ionic compounds usually do not remain as single units. They form three-dimensional (3-D) crystals.”)

Disclaimer:
All answers sourced exclusively from NCERT Class 9 Science — Exploration, Chapter 9: Atomic Foundations of Matter, Pages 162–183. This ensures that you get full marks for your answers

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